Chemicals are a necessary part of maintaining a clean and safe swimming pool. They help to sanitize the water, balance the water chemistry, clarify the water, prevent algae growth and remove stains. Without the use of chemicals, the water in a swimming pool can become cloudy, green, and potentially harmful to swimmers.
However, it is possible to use alternatives to traditional pool chemicals, such as saltwater systems, mineral purifiers, or ozone generators. These systems can reduce the number of chemicals needed to maintain the pool, but they still require some level of chemical maintenance.
It’s important to note that, regardless of the type of pool maintenance system you choose, it’s necessary to test the water regularly and make adjustments as needed to ensure the safety and cleanliness of the pool.
Additionally, it’s important to consult with a professional or follow the manufacturer’s instructions and safety precautions when handling and storing pool chemicals or other pool maintenance products.
Chemicals commonly used to clean and maintain a swimming pool are:
Chlorine
Chlorine is one of the most widely used and effective chemicals for cleaning and sanitizing swimming pools. It is available in various forms, such as chlorine tablets, granules, or liquid, and can be added to the pool directly or through an automated chlorinator system.
Chlorine works by killing bacteria, viruses, and other microorganisms that can make swimmers sick. It also helps to clarify the water by breaking down and removing organic matter, such as sweat, body oils, and other contaminants.
When chlorine is added to the pool, it reacts with the water to form hypochlorous acid (HOCl) and hypochlorite ions (OCl-), which are the active forms of chlorine that sanitize the water. The amount of chlorine needed to maintain a clean and safe pool will depend on factors such as the size of the pool, the number of swimmers, and the weather conditions.

It’s important to test the chlorine level of the pool regularly and to adjust the amount of chlorine added as needed. Additionally, it’s important to follow the manufacturer’s instructions and safety precautions when handling and storing chlorine and to ensure proper ventilation when handling chlorine.
Bromine
Bromine is a chemical that is similar to chlorine and is also used to sanitize and disinfect swimming pools. It is a halogen element like chlorine and is used as a sanitizer to kill bacteria, viruses, and other microorganisms that can make swimmers sick.
Bromine is available in various forms such as bromine tablets, granules, or liquid, and can be added to the pool directly or through an automated brominator system. Bromine has a few advantages over chlorine, such as:
- Less harsh on eyes and skin: Bromine is generally less harsh on swimmers’ eyes and skin than chlorine, which can cause red eyes and skin irritation.
- Less strong smell: Bromine has a less strong and offensive smell than chlorine, which can make the pool area more pleasant to be around.
- Longer lasting: Bromine tends to last longer in the water than chlorine, which means it does not need to be added as frequently.
- Better in hot tubs: Bromine is better in hot tubs and spas than chlorine, as it does not evaporate as quickly in warm water.
However, bromine does have a few disadvantages, such as it can be more expensive than chlorine, and it can be less effective in killing certain types of bacteria. Additionally, bromine can be a little harder to find in some areas.
Like chlorine, it’s important to test the bromine level of the pool regularly and to adjust the amount of bromine added as needed. Additionally, it’s important to follow the manufacturer’s instructions and safety precautions when handling and storing bromine and to ensure proper ventilation when handling it.
pH balancers
pH balancers are chemicals that are used to maintain the pH level of pool water within a specific range, typically between 7.2 and 7.8. pH is a measure of the acidity or basicity of a solution, and it is important to keep the pH level of pool water within this range for several reasons:
- Sanitation: Chlorine is most effective at killing bacteria and other microorganisms when the pH is between 7.2 and 7.8. Outside of this range, chlorine can become less effective, which can lead to the growth of harmful microorganisms in the pool.
- Swimmer comfort: pH levels outside of the 7.2-7.8 range can cause skin irritation, eye irritation, and respiratory problems.
- Protection of pool equipment: pH levels that are too high or too low can cause damage to pool surfaces, equipment, and plumbing.
To raise the pH level of pool water, soda ash (sodium carbonate) or sodium bicarbonate can be added. To lower the pH level, chemicals such as sodium bisulfate or muriatic acid can be used. It’s important to test the pH level of the pool regularly and to adjust the amount of pH balancer added as needed.
Additionally, it’s important to follow the manufacturer’s instructions and safety precautions when handling and storing pH balancer chemicals.

Alkalinity Increasers
Alkalinity increasers are chemicals that are used to increase the total alkalinity of pool water. Total alkalinity is a measure of the ability of water to resist changes in pH, and it is important to keep the total alkalinity within a specific range, typically between 80 and 120 parts per million (ppm).
Alkalinity increasers, such as sodium bicarbonate, help to stabilize the pH level in the pool by providing a buffer against pH fluctuations.
To increase the total alkalinity, sodium bicarbonate can be added to the pool. The amount of alkalinity increaser needed will depend on factors such as the size of the pool and the water chemistry. It’s important to test the total alkalinity of the pool regularly and to adjust the amount of alkalinity increaser added as needed.
Additionally, it’s important to follow the manufacturer’s instructions and safety precautions when handling and storing alkalinity increaser chemicals.
Calcium Hardness Increasers
Calcium hardness increasers are chemicals that are used to increase the calcium hardness in pool water. Calcium hardness is a measure of the amount of calcium dissolved in the water, and it is important to keep the calcium hardness within a specific range, typically between 200 and 400 parts per million (ppm).
Calcium hardness is important for several reasons:
- Protection of pool surfaces: Low calcium hardness can cause corrosion or etching of pool surfaces and equipment, such as tile or plaster. High calcium hardness can cause scaling or cloudy water.
- Swimmer comfort: Low calcium hardness can cause skin irritation and dryness.
- pH balance: Calcium hardness can affect the pH balance of the water.
Calcium hardness increasers, such as calcium chloride, can be added to the pool to increase the calcium hardness level. The amount of calcium hardness increaser needed will depend on factors such as the size of the pool, the water chemistry, and the type of pool surface.
It’s important to test the calcium hardness of the pool regularly and to adjust the amount of calcium hardness increaser added as needed. Additionally, it’s important to follow the manufacturer’s instructions and safety precautions when handling and storing calcium hardness increaser chemicals.
Clarifiers
Clarifiers are chemicals that are used to improve the clarity of pool water by coagulating small particles, such as dirt, algae, and other contaminants, making them easier to filter out. These particles, known as “total suspended solids” (TSS) can make the water appear cloudy or hazy.
There are several types of clarifiers that can be used in swimming pools, including:
- Polymeric clarifiers: These chemicals, also known as flocculants, work by binding small particles together, forming larger particles that can be more easily removed by the pool’s filtration system.
- Enzymatic clarifiers: These chemicals use enzymes to break down organic matter, such as oils and lotions, that can make the water appear cloudy.
- Chitin clarifiers: These chemicals are designed to remove particles that are caused by the exoskeletons of crustaceans, mollusks, and other aquatic organisms.
Clarifiers are added to the pool in small amounts and can be used in conjunction with other pool chemicals, such as chlorine or algaecides.

It is important to follow the manufacturer’s instructions and safety precautions when handling and storing clarifiers and to use the right amount of clarifier to avoid over-clarifying which can cause cloudiness of the water. Additionally, it’s important to run the pool filter for an appropriate amount of time to remove the coagulated particles.
Algaecides
Algaecides are chemicals that are used to kill and prevent the growth of algae in swimming pools. Algae can make the water appear green, cloudy, and slimy, and can also clog filters and pipes, which can lead to damage to the pool surfaces, equipment, and plumbing. Algae can also cause skin and eye irritation, and make the pool water unsanitary.
There are several types of algaecides available for swimming pools, including:
- Copper-based algaecides: These chemicals work by disrupting the photosynthesis process of algae, killing the algae and preventing it from growing.
- Quaternary ammonium compounds (QUATS): These chemicals work by disrupting the cell membrane of algae, killing the algae and preventing it from growing.
- Organic algaecides: These chemicals made from natural ingredients such as rosin, are also effective in killing algae, but tend to be less harsh than copper-based or QUATS algaecides.
Algaecides are added to the pool in small amounts, typically on a weekly or bi-weekly basis, and can be used in conjunction with other pool chemicals, such as chlorine.

It’s important to follow the manufacturer’s instructions and safety precautions when handling and storing algaecides and to use the right amount of algaecide to avoid over-treatment which can cause other issues such as staining, cloudiness, or formation of foam in the water.
Conclusion
In conclusion, chemicals play a crucial role in maintaining a clean and safe swimming pool. Various chemicals are used for different purposes such as sanitizing, balancing water chemistry, clarifying the water, preventing algae growth, and removing stains.
It is important to use the right amount of each chemical, test the pool water regularly, and follow the manufacturer’s instructions and safety precautions when handling and storing pool chemicals. Additionally, it’s also important to consider alternatives to traditional pool chemicals such as saltwater systems, mineral purifiers, or ozone generators.